No doubt, most all of us would say we care more about pleasing God than man. Not to mention pleasing ourself. I find how much I'm invested in this world when something I feel I need or want is threatened.
I also notice this when I can tell I'm not coming off well (not well spoken, smart, interesting, good looking or even competent enough).
Here is an oft quoted scripture I try to remember. Romans 12:2 - And be not conformed to this world; but be ye transformed by the renewing of your mind, that ye may prove what is that good, and acceptable, and perfect, will of God.